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ICM—以应用为导向的高水平创新研究
★ Volume 3 Issue 4 ★
Industrial Chemistry & Materials Volume 3,Issue 4文章正式出版啦!本期共收录2篇Review、1篇Communication和5篇Research paper,文章作者来自南京大学、上海交大、华东理工、中国科学院过程工程所、西班牙赫罗纳大学、意大利米兰比可卡大学等国内外知名机构。欢迎广大读者阅读、下载和分享!
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本期封面
Front cover
本期封面文章来自南京大学马晶教授团队的文章:Coarse-grained models for ionic liquids and applications to biological and electrochemical systems。研究人员综述了离子液体粗粒化模型的发展近况,重点探讨了构建模型的一般流程和相关方法,考虑极化效应的相关策略,机器学习技术在构建模型上的应用,以及模型在电化学和生物体系的应用以及潜在的限制。本图在中央核心区域通过写意的视图风格即展示了离子液体由全原子模型过渡到粗粒化模型的转化过程,同时以突出的视觉元素强调了机器学习技术在模型开发中扮演着日渐重要的作用。两侧图像形象地展现了综述中所强调的模型的应用场景,画风融合了工业元素(如制药工厂和电池)与学术风格(细胞核,超级电容器),体现了科研与实际应用的紧密结合。
See Jing Ma et al., Ind. Chem. Mater., 2025, 3, 383-411.
Back cover
本期封底文章来自中国科学院高能物理研究所核能放射化学实验室的文章:Experimental and theoretical progress about the reduction of Np(VI) with salt-free reagents in PUREX process。研究团队针对PURXE流程中Np的价态复杂、调控困难等问题,从实验和理论方面分别阐述了肼类、羟胺类、醛类、肟类、异羟肟酸类等无盐还原剂将Np(VI)还原为Np(V)的反应动力学及其反应机理。论文封底以核电站为背景,图中反应器直观展示了Np (VI) 经无盐试剂处理转化为 Np (V) 的过程,说明无盐试剂的主要优点为不引入盐分、易分解、选择性好、反应速度快等,有利于简化流程。该综述有助于深入理解PUREX流程中Np的还原动力学,为改进和发展先进PUREX流程提供研究基础。
See Qun-Yan Wu, Wei-Qun Shi et al., Ind. Chem. Mater., 2025, 3, 412-430.
本期内容
01 Review | Page 383-411
Coarse-grained models for ionic liquids and applications to biological and electrochemical systems
南京大学马晶教授团队:原子力场也能“瘦身”?离子液体粗粒化模型及其在生物与电化学领域的新进展
Highlight:
1. 介绍离子液体粗粒化模型的构建流程和不同参数化方法;
2. 总结可极化模型与机器学习技术在离子液体粗粒化模型中的应用与挑战;
3. 概述离子液体粗粒化模型在生物和电化学领域的研究进展,展望开发具有更高精度和更强可迁移性模型的机遇和挑战。
👇点击图片查看图文详解👇
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https://doi.org/10.1039/D5IM00021A
Citation: Ind. Chem. Mater., 2025, 3, 383-411.
02 Review | Page 412-430
Experimental and theoretical progress on the reduction of Np(VI) with salt-free reagents in the PUREX process
中国科学院高能物理研究所核能放射化学实验室:PUREX过程中无盐试剂作用下Np(VI)还原的实验与理论研究进展
Highlight:
This review summarizes the reduction reaction of Np(VI) to Np(V) by hydrazine, hydroxylamine, aldehydes, oximes, hydroxamic acids and their derivatives as well as the reaction kinetics, reaction mechanism and electronic structures.
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https://doi.org/10.1039/D5IM00009B
Citation: Ind. Chem. Mater., 2025, 3, 412-430.
03 Communication | Page 431-439
Imidazolium ligand-modified Cu2O catalysts for enhancing C2+ selectivity in CO2 electroreduction via local *CO enrichment
华东理工李宇航教授团队:咪唑铵配体修饰的CuO2催化剂通过局域*CO富集增强CO2电还原中C2+选择性
Highlight:
Hydrophobic microenvironment engineering on Cu2O via alkyl-imidazolium ionic liquids boosts electrochemical CO2 reduction (CO2RR), achieving 63.3% (alkaline) and 30.7% (acidic) C2 selectivity.
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https://doi.org/10.1039/D5IM00052A
Citation: Ind. Chem. Mater., 2025, 3, 431-439.
04 Paper | Page 440-451
Tuning the band gap energy of CuxInyS for superior photothermocatalytic CO2 conversion to C2H4
中国科学院过程工程所刘瑞霞研究员团队:调节CuxInyS能隙以实现优异的光热催化CO₂转化为C₂H₄
Highlight:
Metal sulfides synthesized hydrothermally enable photothermocatalytic CO2 reduction to ethylene via enhanced multi-electron transfer from negative CB positions.
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https://doi.org/10.1039/D5IM00015G
Citation: Ind. Chem. Mater., 2025, 3, 440-451.
05 Paper | Page 452-463
Systematic investigation of the role of the epoxides as substrates for CO2 capture in the cycloaddition reaction catalysed by ascorbic acid
西班牙Universitat de Girona,Albert Poater教授团队:抗坏血酸催化下环氧化物作为底物参与CO₂环加成反应中作用机制的系统研究
Highlight:
A detailed computational analysis of CO2–epoxide cycloaddition to form cyclic carbonates under mild conditions, identifying in a predictive way key factors affecting reactivity, aiding catalyst design for CO2 valorisation.
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https://doi.org/10.1039/D5IM00037H
Citation: Ind. Chem. Mater., 2025, 3, 452-463.
06 Paper | Page 464-474
Green recovery of all-solid-state sodium-ion batteries/lithium-ion batteries by ionic liquids, deep eutectic solvents and low-melting mixture solvents
廊坊师范学院陈钰副教授团队:利用离子液体、深共熔溶剂和低熔点混合溶剂绿色回收全固态钠离子/锂离子电池
Highlight:
Cathode materials and electrolytes from all-solid-state sodium-ion batteries and lithium-ion batteries are recovered using three types of green solvents: ionic liquids, deep eutectic solvents and low-melting mixture solvents.
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https://doi.org/10.1039/D4IM00149D
Citation: Ind. Chem. Mater., 2025, 3, 464-474.
07 Paper | Page 475-484
Nitrogen doped hierarchical porous carbon for supercapacitors and zinc ion hybrid capacitors
东北林业大学吴小亮教授团队:孔道离子高速公路+氮掺杂电子闸门:多级碳结构同步优化双电层与赝电容
Highlight:
1. 以琼脂(海藻提取物)为碳源,尿素为氮源,一步碳化活化法实现氮掺杂多孔碳(NPC)的简易合成;
2. 分级孔道-杂原子协同增效,三维互联分级孔结构加速离子传输,高活性官能团为离子吸附提供丰富活性位点;
3. 双模式储能性能突破,具有高能量密度及优异的循环稳定性。
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https://doi.org/10.1039/D5IM00044K
Citation: Ind. Chem. Mater., 2025, 3, 475-484.
08 Paper | Page 485-497
Amorphous nanostructured Ni–Fe oxide as a notably active and low-cost oxygen evolution reaction electrocatalyst for anion exchange membrane water electrolysis
意大利University of Milano-Bicocca,Carlo Santoro教授团队:非晶态纳米结构Ni–Fe氧化物:用于阴离子交换膜水电解的高活性低成本析氧反应电催化剂
Highlight:
Amorphous NiFe oxides simplistically synthesized through the sol–gel method with varying Ni/Fe ratios demonstrated remarkable electrocatalytic performance towards the oxygen evolution reaction in an anion exchange membrane water electrolyzer.
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https://doi.org/10.1039/D5IM00008D
Citation: Ind. Chem. Mater., 2025, 3, 485-497.
ICM整期浏览
1. ICM 图文目录 | Volume 3 Issue 3
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▶▷ https://pubs.rsc.org/en/journals/journalissues/im#!issueid=im003003&type=current&issnprint=2755-2608
2. ICM 图文目录 | Volume 3 Issue 2
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▶▷ https://pubs.rsc.org/en/journals/journalissues/im#!issueid=im003002&type=current&issnprint=2755-2608
3. ICM 图文目录 | Volume 3 Issue 1
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▶▷ https://pubs.rsc.org/en/journals/journalissues/im#!issueid=im003001&type=current&issnprint=2755-2608
4. ICM 图文目录 | Volume 2 Issue 4
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▶▷ https://pubs.rsc.org/en/journals/journalissues/im#!issueid=im002004&type=current&issnprint=2755-2608
期刊简介
Industrial Chemistry & Materials (ICM) 目前已被ESCI、EI、CSCD、美国化学文摘(CA)、DOAJ等数据库检索,首个影响因子11.9,位列Q1区,入选2024年中国科技期刊卓越行动计划高起点新刊项目。是中国科学院主管,中国科学院过程工程研究所主办,英国皇家化学会(RSC)全球出版发行的Open Access英文期刊,由中国科学院过程工程研究所张锁江院士担任主编。ICM 以化学、化工、材料为学科基础,以交叉为特色,以应用为导向,重点关注工业过程中化学问题、高端材料创制中过程科学的国际前沿和重大技术突破,目前对读者作者双向免费。欢迎广大科研工作者积极投稿、阅读和分享!
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