2025年6月21日，Elsevier 旗下top期刊《Journal of Energy Storage》在线发表了云南师范大学化学与化工学院高端引进人才李如春博士和暨南大学化学与材料学院袁定胜合作的最新研究成果《Bimetal heterostructured nanoparticles anchored hierarchical carbon nanospheres with abundant active sites for high-performance liquid/flexible zinc-air batteries》。云南师范大学化学化工学院李如春博士为第一作者兼通讯作者，暨南大学化学与材料学院袁定胜为共同通讯作者。
The development of highly active bifunctional electrocatalysts is crucial to the sluggish oxygen reduction reaction/oxygen evolution reaction (ORR/OER) for efficient wearable Zn–air batteries (ZAB). The Fe-Nx-C moieties anchored on carbon supports emerge as a desirable alternative to ORR catalysts but its OER activity suffers from low catalytic performance and stability. Herein, a N-doped carbon-encapsulated Fe3C and MnO nanoparticles composite (FeMn-NC) was developed using a simple one-step pyrolysis of the self-sacrificial template. The obtained FeMn-NC possesses a hierarchical porous structure with a large specific surface area and rich pyridinic N, which are favorable for the exposure of the active sites. The introduction of the Fe3C/MnO interface can regulate the charge redistribution to promote ORR/OER kinetics, which is confirmed by theoretical calculations. The obtained FeMn-NC exhibits an excellent bifunctional ORR/OER activity in alkaline electrolytes. The assembled liquid ZAB with the FeMn-NC as the cathode can achieve an ultrahigh specific capacity of 792.7 mAh g−1 and charge-discharged stability up to 800 h at 10 mA cm−2 (2400 cycles). Furthermore, the corresponding flexible solid-state ZAB provides a stable open-circuit voltage of 1.50 V and a specific capacity of 676.1 mAh g−1 at 1.0 mA cm−2 with good cycling stability. This work offers a simple strategy to synthesize hierarchical porous materials with highly active bifunctional properties, which can be applied in other electrochemical energy devices.
扩展阅读：
云师大化工学院李如春在《Journal of Colloid and Interface Scienc》发表最新研究成果
云师大化工学院李如春在《Separation and Purification Technology》发表最新研究成果
云师大化工学院李如春博士在top期刊《Chinese Chemical Letters》发表最新研究成果
中山大学博士、武汉理工大学博士后李如春副教授加盟云南师范大学
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