Chem. Soc. Rev. 09年第5期来了个Metal Organic Frameworks专题，足见MOF的热度，个人对此很感兴趣，最喜欢YAGHI等人艺术家一样的思路和方法。特此贴出来图文摘要，算是备份，顺便认识下对此有兴趣的老师和朋友。

 http://www.rsc.org/Publishing/Journals/cs/

Jeffrey R. Long and Omar M. Yaghi,  Chem. Soc. Rev., 2009, 38, 1213
DOI: 10.1039/b903811f

Guest editors Jeffrey Long and Omar Yaghi introduce this themed issue of Chemical Society Reviews on metal–organic frameworks (MOFs).


ViewpointDesign of MOFs and intellectual content in reticular chemistry: a personal view
Michael OKeeffe,  Chem. Soc. Rev., 2009, 38, 1215
DOI: 10.1039/b802802h

A personal perspective on the ideas leading to the development of reticular chemistry. The feasibility of achieving targeted materials with predetermined metrics and functionality by designed synthesis is defended.


Tutorial ReviewsInfinite coordination polymer nano- and microparticle structures
Alexander M. Spokoyny, Dongwoo Kim, Abdelqader Sumrein and Chad A. Mirkin,  Chem. Soc. Rev., 2009, 38, 1218
DOI: 10.1039/b807085g

Synthesis, properties and emerging applications of metal–organic infinite coordination polymer nano- and microparticle structures.


Polymerization reactions in porous coordination polymers
Takashi Uemura, Nobuhiro Yanai and Susumu Kitagawa,  Chem. Soc. Rev., 2009, 38, 1228
DOI: 10.1039/b802583p

Recent developments in polymerizations within the nanochannels of porous coordination polymers (PCPs) are covered in this tutorial review.


Using molecular simulation to characterise metal–organic frameworks for adsorption applications
Tina Düren, Youn-Sang Bae and Randall Q. Snurr,  Chem. Soc. Rev., 2009, 38, 1237
DOI: 10.1039/b803498m

This tutorial review examines the power of molecular simulation for characterizing metal–organic frameworks and providing insights into design principles for adsorption applications.


Enantioselective catalysis with homochiral metal–organic frameworks
Liqing Ma, Carter Abney and Wenbin Lin,  Chem. Soc. Rev., 2009, 38, 1248
DOI: 10.1039/b807083k

Recent advances in homochiral metal–organic frameworks herald the development of highly efficient heterogeneous asymmetric catalysts for the production of optically pure organic molecules.


Critical ReviewsSecondary building units, nets and bonding in the chemistry of metal–organic frameworks
David J. Tranchemontagne, José L. Mendoza-Cortés, Michael OKeeffe and Omar M. Yaghi,  Chem. Soc. Rev., 2009, 38, 1257
DOI: 10.1039/b817735j

We provide a comprehensive geometric examination of secondary building units that are expected to be useful in the designed synthesis of metal–organic frameworks.


Industrial applications of metal–organic frameworks
Alexander U. Czaja, Natalia Trukhan and Ulrich Müller,  Chem. Soc. Rev., 2009, 38, 1284
DOI: 10.1039/b804680h

An overview of potential applications for metal–organic frameworks in the chemical industry is presented.


Hydrogen storage in metal–organic frameworks
Leslie J. Murray, Mircea Dinc and Jeffrey R. Long,  Chem. Soc. Rev., 2009, 38, 1294
DOI: 10.1039/b802256a

An overview of the development of microporous metal–organic frameworks for hydrogen storage applications.


Postsynthetic modification of metal–organic frameworks
Zhenqiang Wang and Seth M. Cohen,  Chem. Soc. Rev., 2009, 38, 1315
DOI: 10.1039/b802258p

Postsynthetic modification of MOFs is rapidly becoming one of the most important approaches for discovery and functionalization of MOFs.


Luminescent metal–organic frameworks
M. D. Allendorf, C. A. Bauer, R. K. Bhakta and R. J. T. Houk,  Chem. Soc. Rev., 2009, 38, 1330
DOI: 10.1039/b802352m

Luminosity in metal–organic frameworks resulting from their multifaceted structure creates potential for applications as diverse as chemical and radiation sensors, medical imaging, and electro-optical devices.


Magnetic metal–organic frameworks
Mohamedally Kurmoo,  Chem. Soc. Rev., 2009, 38, 1353
DOI: 10.1039/b804757j

Cobalt(II) in metal–organic frameworks provides unusual and exotic magnetism in addition to all the known ground-states.


Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences
Gérard Férey and Christian Serre,  Chem. Soc. Rev., 2009, 38, 1380
DOI: 10.1039/b804302g

The breathing of solids gives a new dimension to MOFs. The rules governing this effect are established and explain the various applications of this phenomenon.


Design and synthesis of metal–organic frameworks using metal–organic polyhedra as supermolecular building blocks
John J. Perry IV, Jason A. Perman and Michael J. Zaworotko,  Chem. Soc. Rev., 2009, 38, 1400
DOI: 10.1039/b807086p

There is plenty of room in the middle: supermolecular building blocks can afford MOFs with enhanced scale and structural control.


Thin films of metal–organic frameworks
Denise Zacher, Osama Shekhah, Christof Wöll and Roland A. Fischer,  Chem. Soc. Rev., 2009, 38, 1418
DOI: 10.1039/b805038b

The fabrication of thin film coatings of metal–organic frameworks (MOFs) on various substrates is reviewed. Typically, MOF films are grown by immersion of the substrates in pre-treated solvothermal mother liquors of the chosen MOF. Alternatively, flat homogenous films with thicknesses up to ca. 100 nm are grown by a stepwise layer-by-layer method.


Phosphonate and sulfonate metal organic frameworks
George K. H. Shimizu, Ramanathan Vaidhyanathan and Jared M. Taylor,  Chem. Soc. Rev., 2009, 38, 1430
DOI: 10.1039/b802423p

Phosphonate and sulfonates, with their 3-D ligating ability, form MOFs that span a range from zeolite-like to flexible crystalline solids.


Metal–organic framework materials as catalysts
JeongYong Lee, Omar K. Farha, John Roberts, Karl A. Scheidt, SonBinh T. Nguyen and Joseph T. Hupp,  Chem. Soc. Rev., 2009, 38, 1450
DOI: 10.1039/b807080f

Critically surveying the status of metal organic frameworks as catalytic materials.


Recent advances on simulation and theory of hydrogen storage in metal–organic frameworks and covalent organic frameworks
Sang Soo Han, José L. Mendoza-Cortés and William A. Goddard III,  Chem. Soc. Rev., 2009, 38, 1460
DOI: 10.1039/b802430h

Different ways of increasing the hydrogen storage in microporous material MOFs and COFs are explored using a variety of theoretical and computational methods.


Selective gas adsorption and separation in metal–organic frameworks
Jian-Rong Li, Ryan J. Kuppler and Hong-Cai Zhou,  Chem. Soc. Rev., 2009, 38, 1477
DOI: 10.1039/b802426j

This review summarizes the advances in the study of selective gas adsorption and separation using metal–organic frameworks (MOFs), a new type of adsorbent with intriguing application potential.

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