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Frontiers of Chemical Science and Engineering 2015年第4期已经出版。本期刊载了来自美国德克萨斯农工大学康莫斯分校化学系的Ben W.-L. Jang教授的最新研究成果。Jang教授等利用置换(galvanic replacement)和简单传统的等体积浸渍(incipientwetness impregnation)技术合成了一种氧化铝负载的Cu-Pd单原子合金(single atom alloy)催化剂。孤立的合金Pd原子结构独特,能够离解氢分子并将解离后的氢原子传递到邻近的Cu原子上,同时,Pd原子还能活化邻近的Cu原子,从而实现在Cu原子上进行选择性加氢,因此合成的Cu-Pd催化剂对乙炔选择性加氢表现出优良的选择性以及活性。
具体内容请参见 Xinxiang Cao, Arash Mirjalili, James Wheeler, Wentao Xie,Ben W.-L. Jang. Investigation of the preparationmethodologies of Pd-Cu single atom alloy catalysts for selective hydrogenationof acetylene. Front. Chem. Sci. Eng., 2015, 9(4): 442-449.
此外,本期还刊载了以下文章:
REVIEW ARTICLE
Cationic and amphipathic cell-penetrating peptides (CPPs): Their structures and in vivo studies in drug delivery.Jennica L. Zaro,Wei-Chiang Shen
SERS nanoprobes for bio-application.Han-Wen Cheng,Jin Luo,Chuan-Jian Zhong
RESEARCH ARTICLE
Alkaline modification of ZSM-5 catalysts for methanol aromatization: The effect of the alkaline concentration. Zhenhao Wei,Tengfei Xia,Minghui Liu,Qingsheng Cao,Yarong Xu,Kake Zhu,Xuedong Zhu
Selective conversion of cellulose to hexitols over bi-functional Ru-supported sulfated zirconia and silica-zirconia catalysts. Zhiqiang Song,Hua Wang,Yufei Niu,Xiao Liu,Jinyu Han
Surface molecularly imprinted polymers for solid-phase extraction of (--)-epigallocatechin gallate from toothpaste. Yunling Gao,Ying Hu,Kejian Yao
Extraction of hydrogen chloride by a coupled reaction-solvent extraction process. Yunzhao Li,Xingfu Song,Guilan Chen,Shuying Sun,Yanxia Xu,Jianguo Yu
Organogelators based on p-alkoxylbenzamide and their self-assembling properties. Yan Zhai,Wei Chai,Wenwen Cao,Zipei Sun,Yaodong Huang
Size-controlled green synthesis of silver nanoparticles assisted by L-cysteine. Wenchao Zhang,Lin Zhang,Yan Sun
Enhanced production of β-glucuronidase from Penicillium purpurogenum Li-3 by optimizing fermentation and downstream processes. Shen Huang,Xudong Feng,Chun Li
DsbA-DsbAmut fusion chaperon improved soluble expression of human trypsinogen-1 in Escherichia coli. Ye Liu,Wenyong Zhang,Xubin Yang,Guangbo Kang,Damei Wang,He Huang
Effects of operational and structural parameters on cell voltage of industrial magnesium electrolysis cells. Ze Sun,Chenglin Liu,Guimin Lu,Xingfu Song,Jianguo Yu
Orderly decorated nanostructural photoelectrodes with uniform spherical TiO2particles for dye-sensitized solar cells. A. M. Bakhshayesh,S. S. Azadfar
敬请阅览。
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