https://www.sciencedirect.com/science/article/pii/S0021951723000428

Abstract

Arrhenius plots estimate the apparent activation energy (Ea) of catalytic reactions. The R-squared value (r2) often accompanies the Arrhenius plot to support its validity. However, no paper has quantitatively presented the minimum data points and the minimum r2 to validate the Ea. In this study, statistical analysis quantitatively visualized the relationship between the number of data points (np), r2, and the reliability of Ea. When np ≧ 5, the risk of underestimating the variance of Ea is suppressed significantly, making the Ea and its variance more reliable. Furthermore, to claim that two values of Ea are statistically different, the minimum required r2 was formulated and plotted as a function of Ea and np. The proposed formulas couple np and r2 to validate Ea quantitatively. This method is superior to the empirical method using r2 alone. This study produces tangible and quantitative guidance to control the reliability of the Arrhenius plot.