2024年10月3日,Elsevier旗下top期刊《Journal of Rare Earths》在线发表了云南师范大学化学化工学院刘丰祎教授、张旭锋副教授最新研究成果《In-situ preparation of lanthanide luminescent MOF hydrogel for aldehyde detection》。云南师范大学化学化工学学院为第一作者单位,刘丰祎教授、张旭锋副教授为共同通讯作者。
Abstract
Metal-organic frameworks (MOFs) usually exist in the state of powder or crystal. When they are exposed to hydrophilic solvents, their structure will change and become unstable. Therefore, it is a challenge to construct MOF materials with tunable mechanical properties. Herein, we report in-situ growth lanthanide metal-organic framework (LnMOF) in sodium alginate (SA) and polyvinyl alcohol (PVA) hydrogel matrix. The prepared composite hydrogel not only displays characteristic lanthanide narrow-band emission under ultraviolet light, but also demonstrates excellent mechanical properties. The addition of LnMOF significantly enhances the compressive strength of the hydrogel (from 0.75 to 7.32 MPa). Furthermore, the composite hydrogel shows highly selective recognition of glutaraldehyde and gaseous formaldehyde at room temperature. The detection limits (LOD) of SP-EuMOF for glutaraldehyde and formaldehyde are 0.27 and 0.22 ppm, respectively. Based on these results, the LnMOF composite hydrogel is deemed to have significant potential as a fluorescent sensor for both glutaraldehyde and formaldehyde detection.
云师大化工学院张旭锋副教授在《J. Agric. Food Chem.》上发表最新研究成果
云师大化工学院刘丰祎、张旭锋副教授在《Journal of Rare Earths》上发表最新研究成果Tough lanthanide luminescent hydrogel for... - 百度学术
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